catena-Poly[[[diaquamanganese(II)]-bis[μ-1,3-bis(1H-imidazol-1-ylmethyl)benzene-κ2N3:N3′]] dinitrate]

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Crystal structure of catena-poly[[[tetra­aqua­zinc(II)]-μ-1,4-bis­[4-(1H-imidazol-1-yl)benzo­yl]piperazine] dinitrate monohydrate]

In the title polymeric complex, {[Zn(C24H22N6O2)(H2O)4](NO3)2·2H2O} n , the Zn(II) cation, located about a twofold rotation axis, is coordinated by two imidazole groups and four water mol-ecules in a distorted N2O4 octa-hedral geometry; among the four coordinate water mol-ecules, two are located on the same twofold rotation axis. The 1,4-bis-[4-(1H-imidazol-1-yl)benzo-yl]piperazine] ligand is c...

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catena-Poly[[[diaqua­manganese(II)]-bis­[μ-1,3-bis­(1H-imidazol-1-ylmeth­yl)benzene-κ2 N 3:N 3′]] dinitrate]

In the title compound, {[Mn(C(14)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Mn(II) ion is located on an inversion center and is coordinated by four N atoms from four 1,3-bis-(1H-imidazol-1-ylmeth-yl)benzene (L) ligands and two water mol-ecules in a distorted octa-hedral geometry. Two L ligands are related by a centre of symmetry and bridge Mn(II) ions, forming a positively charged polymeric ch...

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catena-Poly[[zinc(II)-bis­[μ-1,3-bis­(imidazol-1-ylmeth­yl)benzene-κ2 N 3:N 3′]] dinitrate methanol solvate]

In the title coordination compound, {[Zn(C(14)H(14)N(4))(2)](NO(3))(2)·CH(3)OH}(n), the cationic complex forms a looped chain containing 24-membered M(2)L(2) rings. The ligand adopts two distinct conformations that are alternated in subsequent loops. The Zn(II) ion displays a slightly distorted tetra-hedral geometry being coordinated by four N atoms from four 1,3-bis-(imidazol-1-ylmeth-yl)benze...

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13-(Imidazol-1-yl)-11,13-di­hydro­melampomagnolide B monohydrate

The title compound, C18H24N2O4·H2O {systematic name: (1aR,7aS,8R,10aS,10bS,E)-5-hy-droxy-methyl-8-[(1H-imidazol-1-yl)meth-yl]-1a-methyl-2,3,6,7,7a,8,10a,10b-octa-hydro-oxireno[2',3':9,10]cyclo-deca-[1,2-b]furan-9(1aH)-one monohydrate}, an imidazole derivative of melampomagnolide B was synthesized under Michael addition conditions. The mol-ecule is built up from fused ten-, five- (lactone) and t...

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catena-Poly[(trans-diaqua­cadmium)-bis­{μ-5-[4-(1H-imidazol-1-yl)phen­yl]tetra­zol-1-ido}]

In the title compound, [Cd(C(10)H(7)N(6))(2)(H(2)O)(2)], the Cd(II) atom lies on an inversion centre and is coordinated by four N atoms from 5-[4-(1H-imidazol-1-yl)phen-yl]tetra-zol-1-ide ligands and two O atoms from the coordinated water mol-ecules in an octa-hedral arrangement. The complex polymeric chains are inter-connected via inter-molecular water O-H⋯N hydrogen bonds into a three-dimensi...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811039882